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I also really liked Vermont while I lived there, and everything that you mentioned are great features. That said, the state (and much of New England) is overwhelmingly white. I am white-passing, but my spouse is not, and they felt consistently othered while we lived there. Not in an aggressive or hateful way, but in a “strangers see me as a novelty” way that you tend to get in homogenous communities. Burlington is probably a bit more diverse than the relative middle of nowhere where we lived, so your mileage may vary.
Probably around 72 hours. I had a severe bout of depression a decade ago. I’m not certain how long I went without food because my memory of that period is hazy, but I barely ate or left my bed for a week. A few years before that I had salmonella poisoning (do NOT recommend) and didn’t eat or really even sleep for something like 10 days. I drank sugar water and electrolytes to stay alive but I still lost about 10 kilos.